Synthesis, Microstructure and Properties of Poly (L-lactic acid-co-α-alanine) Obtained by Direct Melting Copolymerization
A new poly(ester amide)s (PEA) derived from L-lactic acid and α-alanine have been synthesized by melting copolymerization with p-toluenesulfonic acid (TSA) with stannous chloride (SnCl2) as catalyst. The products were analyzed by NMR, FT IR techniques. The effects of the content of α-alanine (L-Ala) on the copolymers structure were studied. Being the phosphate buffered saline (pH=7.2) as the degradation solution, the degradation rate speed up with the increasing the content of the α-alanine.
polylactide alanine polyester amidea melting copolymerizationa biodegradable
Lian Liu Xiewei Chen Pei Wang Zhiyong Wei Chunyun Liu Min QI
Department of Materials Science and Engineering, Dalian Maritime University,Dalian 116026, China School of Automotive Engineering, Dalian University of Technology, Dalian 116024, China School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
国际会议
11th IUMRS International Conference in Asia(第十一届国际材联亚洲材料大会 IUMRS-ICA 2010)
青岛
英文
390-393
2010-09-25(万方平台首次上网日期,不代表论文的发表时间)