Growing Behaviors of Oxidation Film on the Surface of Liquid Sn-0.68Cu-0.3Ag-X Solder
A lead-free hypoeutectic solder Sn-0.3Ag-0.68Cu-X with low sliver content was prepared by a new process. By the method of skimming surface oxidation film at static state, the growing behaviors of oxidation film on the surface of liquid solder alloy were studied. The experimental results show that the growth rate of oxidation film on the surface of liquid solder decreases greatly after surface modification process. Before the surface modification process, the growth behaviors of oxidation film on the surface of liquid solder obey parabolic law which changes with variation of time. After surface modification, the growth behavior of oxidation film of liquid solder is transformed into obeying logarithmic law. The formation rate of oxidation slag on the surface of liquid Sn-0.3Ag-0.68Cu-X solder can be reduced to 0.36 mg/cm2.min at 260 oC under standard test conditions. Conceptually, the atomic-doping X (X=Ga, In, Bi, Ge, Sb, Ni and P) was absorbed to the surface of liquid solder according to Gibbs absorption equation and entered into oxidation film, which is prone to form more compact oxidation film to prevent the oxidation on the surface of liquid solder.
Sn-Cu-Ag solder Liquid metal Oxidation film Growing behavior
Changhua Du Limeng Yin Yi Luo Fang Chen Haijian Zhao
School of Materials Science and Engineering, Chongqing University of Technology,Chongqing 400050, Ch School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology,Chong School of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400050, C
国际会议
11th IUMRS International Conference in Asia(第十一届国际材联亚洲材料大会 IUMRS-ICA 2010)
青岛
英文
85-89
2010-09-25（万方平台首次上网日期，不代表论文的发表时间）