Pinning effects on the dielectric and ferroelectric properties of Mn-doped Ba(Zr0.06Ti0.94)O3 ceramics
Lead-free ceramics with the composition of Mn-doped Ba(Zr0.06Ti0.94)O3 – xmol％MnO2 (BZT6-xMn, x=0, 1 and 2) have been synthesized by a mixed oxide process. Structure and micrograph characterization were examined using X-ray diffraction (XRD) and scanning electron microscopy (SEM), which revealed that all samples have the orthorhombic phase with dense and the uniform microstructure. The grain size of Mn-doped BZT6 ceramics decreased with increasing MnO2 doping. The effect of MnO2 doping on the dielectric and ferroelectric properties was also investigated. The maximum dielectric permittivity decreased dramatically with increasing MnO2 doping in the BZT6 ceramics. A peculiar double-hysteresis-like loop was observed. Mn ions as acceptor doping occupy the B site of ABO3 in the form of Mn2+ and Mn3+, which brought an increase in the oxygen vacancies concentration. The defect dipole model was explained the pinning mechanism.
Ba(Zr Ti)O3 Mn-doping ceramics dielectrics ferroelectrics pinning effect
S.J. Kuang X.G. Tang J.B. Wu Y.P. Jiang Q.X. Liu
School of Physics & Optoelectric Engineering, Guangdong University of Technology,Guangzhou Higher Ed School of Physics & Optoelectric Engineering, Guangdong University of Technology, Guangzhou Higher E
国际会议
11th IUMRS International Conference in Asia(第十一届国际材联亚洲材料大会 IUMRS-ICA 2010)
青岛
英文
354-358
2010-09-25（万方平台首次上网日期，不代表论文的发表时间）