Insights into the Formation of Titanium in the TiROTM Process
The TiROTM process is a new process being developed at CSIRO for the direct continuous production of titanium powder. The reaction takes place in a fluidised bed reactor (FBR) at temperatures between 650℃ and 712℃. Titanium tetrachloricle and magnesium powder with a d50 around 150 μm are injected into the FBR with an argon carrier gas. A seed bed of pre-existing product is required to initiate the reaction. The product particles are spheroidal and range in size with d50 from 300 to 700 μm. They comprise a matrix of magnesium chloride with micron sized titanium particles uniformly dispersed throughout. The likely reaction mechanism is discussed. Environmental Scanning Electron Microscopy (ESEM) and electron probe microanalysis of polished sections of product particles indicates the reaction starts on the surface of freshly added magnesium particles which become encapsulated with product. The reaction appears to continue on two fronts as the magnesium is consumed;at the interface o the magnesium core and surrounding reaction products and,at the outer surface of the particle. Completely reacted particles contain some or no internal voidage. Product particles are larger than predicted based on reaction stoichiometry. Their growth is attributed to agglomeration within the bed.
TiROTM process reaction mechanism titanium powder fluidised bed electron probe microanalysis
Christian Doblin Ain Beruldsen
Commonwealth Scientific and Industrial Research Organisation Light Metals Flagship,Clayton 3168,Aust Commonwealth Scientific and Industrial Research Organisation Process Science and Engineering,Clayton
国际会议
The 12th World Conference Titanium(第十二届世界钛会 Ti-2011)
北京
英文
1735-1739
2011-06-19（万方平台首次上网日期，不代表论文的发表时间）