Thermal and Electrical Properties of PVDF-HFP-LiCF3SO3-ZrO2 Nanocomposite Solid Polymer Electrolytes

摘要：

ZrO2 nano sized filler of different amounts is introduced into solid polymer electrolytes of PVDF-HFP-LiCF3SO3-ZrO2. It is observed that the conductivity of the electrolytes varies with ZrO2 content and temperature. The highest room temperature conductivity achieved is in the order of 10-3 S cm-1 which is an increase of seven orders of magnitude compared to the conductivity of PVDF-HFP-LiCF3SO3 (without filler). The temperature dependent conductivity follows the Vogel Tamman Fulcher relationship which can be described by the free volume theory. Transference number measurements using DC polarization method show that the nanocomposite polymer electrolytes are ionic conductors. Differential Scanning Calorimetry results show that the degree of crystallinity is slightly affected by the addition of ZrCh nano filler.

关键词： Nanosized filler Differential Scanning Calorimetry Impedance spectroscopy ionictransference number

作者: S. Ibrahim N.S. Mohamed

作者单位: Institute of Graduate Studies,University of Malaya,50603 Kuala Lumpur,Malaysia Center for Foundation Studies in Science,University of Malaya,50603 Kuala Lumpur,Malaysia

会议类型: 国际会议

会议名称: 2010 International Conference on Material and Manufacturing Technology(2010材料与制造技术国际会议 ICMMT2010)

会议地点: 重庆

会议语种:英文

页码: 526-530

在线出版日期: 2010-09-17（万方平台首次上网日期，不代表论文的发表时间）