Interaction of ions in molten slag, salts and oxide compounds on diffusion

摘要：

The diffusion of a ion in slag, salts and oxide compounds is influenced from other ions in the surroundings. The linear relations between the fluxes and the forces of ions are defined as the phenomenological equations. The proportional coefficients named as the transport coefficients represent the interaction of ions on diffusion. The transport coefficients between i ion and j ion are reciprocal and the relation is called as the Onsagers reciprocal theorem. The fluxes of ions are defined on a coordinate and one flux is not independent. The transport coefficients should be satisfied the entropy production on diffusion. The transport coefficients can be calculated from some of the transport properties such as electrical conductivity, transference numbers, tracer diffusivities, interdiffusivities. Others can be determined from the transport coefficients. The diagonal terms in the transport coefficients are positive and the other terms are positive or negative. The values of transport coefficients in some slag, salts and oxide compounds are examined from the non-equilibrium thermodynamics.

关键词： irreversible thermodynamics transport coefficients diffusion electric conductivity transference number

作者: Kazuhiro Nagata

作者单位: Department of Conservation of the Heritage, Tokyo University of the Arts, Tokyo 110-8714, Japan

会议类型: 国际会议

会议名称: Ninth International Conference on Molten Slags,Fluxes and Salts(第九届国际熔渣、溶剂与熔盐学术会议 MOLTEN12)

会议地点: 北京

会议语种:英文

页码: 1-9

在线出版日期: 2012-05-27（万方平台首次上网日期，不代表论文的发表时间）