Selectivities for Selenium-catalyzed Reactions of Nitroaromatics with Carbon Monoxide
Introduction Nitroaromatics are very important industrial chemicals. Their reduction to amines is a crucial way to the downstream products. Further reaction of amines with carbonylation reagents (e.g. phosgene and urea) produces various useful fine chemicals and bioactive chemicals, including polyurenanes, drugs and pesitirides. In the course of our investigations on selenium (Se)-catalyzed reactions with carbon monoxide, we found that both reduction reactions and carbonylation reactions of nitroaromatics could occur in the Se/CO system. Herein, we report the selectivities for Se-catalyzed reactions of nitroaromatics with carbon monoxide in details.
Liu X Z Wang X F Ling G Xue Y Li P Yuan X H Lu S W
National Engineering Research Center for Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, Liaoning 116011, China
国际会议
苏州
英文
125-126
2011-10-23（万方平台首次上网日期，不代表论文的发表时间）