Economical and recyclable graphene oxide-based nanocomposites catalyzed Ullmann reaction of aryl chloride in hmim Tf2N/supercritical carbon dioxide system

摘要：

Palladium nanoparticles (Pd NPs)/graphene oxide (GO) nanocomposites catalyzed Ullmann reaction of aryl chloride in hmimTf2N/supercritical carbon dioxide (ScCO2) system were developed. The hmimTf2N/ ScCO2 system showed superior competitiveness in product separation, catalyst recycling as well as environmental consideration. Further investigations showed that GO could replace the traditional active hydrogen donor readily with improved product separation efficiency. The use of hmimTf2N led to obvious improved stability of the catalyst. Carbon dioxide was found to significantly promote the selectivity of the graphene oxide-based nanocomposites catalyzed Ullmann reaction of aryl chloride.

关键词： graphene oxide nanocomposites Ullmann Aryl

作者: CHENG Jinsheng DU Jin

作者单位: Zhejiang Chinese Medical University, Hangzhou 310053, China Department of Chemistry, Tsinghua Univer Zhejiang Chinese Medical University, Hangzhou 310053, China

会议类型: 国际会议

会议名称: The 3rd Asian Conference on Molten Salts and Ions Liquids 2011(第三届亚洲熔盐与离子液体会议)

会议地点: 哈尔滨

会议语种:英文

页码: 156-163

在线出版日期: 2011-01-06（万方平台首次上网日期，不代表论文的发表时间）