Thermoelectric Property of A-Site Deficient Zn0.5Rh2O4
Introduction Thermoelectric materials have been attracted for recycling energy in exhausting heat by thermal-electric conversion effect, which can be closely used and be considered as a new energy resource in human lives. The thermal-electric conversion efficiency is represented by a dimensionless figure of merit: ZT=S2a T/K, where S, a and K are Seebeck coefficient, electrical conductivity, and thermal conductivity, respectively. Accordingly, thermoelectric materials should be designed with higher S, a and lower K. According to the classical semiconductor theory, heavily doped semiconductors having carrier concentrations (n) of ~ 1019 cm3 are candidates for high-ZT materials 1, but metallic materials are not. Thus the discovery of large S (~ 100 |JY/K at 300 K) in NaxCoO2, showing metallic a with n of ~ 1021 cm3, has attracted much attention for its origin of high ZT 2.
Yuta Nakamura Kakemoto Hirofumi
Hiroshi Irielnterdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi Clean Energy Research Center, University of Yamanashi
国际会议
天津
英文
146-148
2011-09-16(万方平台首次上网日期,不代表论文的发表时间)