Photocatalysis of sulfones for the utilization of the oxidized sulfur compounds by oxidative desulfurization of fuel oil

摘要：

Photocatalysis of dibcnzothiophcnc (DBT) sulfonc and bcnzothiophcnc (BT) sulfonc for the utilization of the oxidized sulfur compounds by oxidative desulfurization of fuel oil have been investigated. Results show that DBT sulfonc, when dissolved in 2propanol and photoirradiatcd with high-pressure mercury lamp, can be converted completely into biphenyl in 5 h. However, the photoconvcrsion of BT sulfonc can be up to 100 ％ only in 10 min. The reaction conditions, such as the time of N2 gas bubbled through the solution, distance between the high-pressure mercury lamp and the tube, photoirradiation time and the concentration of sulfones, arc all impacted on the photoconversion of DBT sulfonc and BT sulfonc.

关键词： Photocatalysis Sulfone Oxidative desulfurization Fuel oil

作者: Jianghua Qiu Yuqin Zhang Guanghui Wang Danlin Zeng Bencai Lu Qina Li

作者单位: Hubei Coal Conversion and New Carbon Materials Key Laboratory, College of Chemical Engineering and Technology Wuhan University of Science and Technology Wuhan 430081, P.R.China

会议类型: 国际会议

会议名称: 2011 IEEE 2nd International Conference on Computing，Control and Industrial Engineering(CCIE 2011)(第二届计算、控制与工业工程国际会议)

会议地点: 武汉

会议语种:英文

页码: 259-262

在线出版日期: 2011-08-20（万方平台首次上网日期，不代表论文的发表时间）