Synthesis and Characteristic on Primary-hydroxyl Terminated GAP

摘要：

In order to improve mechanical properties of glycidyl azide polymer (GAP), primary-hydroxyl terminated GAP was synthesized utilizing the reaction between hydroxyls and isocyanates. FTIR analysis showed that secondary-hydroxyl transformation is entired. Maximum elongation measurement indicated that mechanical properties of cured primary-hydroxyl terminated GAP film excel in that of cured secondary-hydroxyl terminated GAP system. Swelling rate of primary-hydroxyl system is lower than that of secondary-hydroxyl system in THF solution. It was resultant that higher activity of primary-hydroxyl optimizes the network structure of GAP binder system and increased the strain and stress, compared with secondary-hydroxyl terminated GAP system.

作者: SHAN Zhongqing ZHAI Jinxian YANG Rongjie LI Xiaodong

作者单位: School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 10081, China

会议类型: 国际会议

会议名称: 2011 International Autumn Seminar on Propellants,Explosives and Pyrotechnics(2011国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 南京

会议语种:英文

页码: 129-132

在线出版日期: 2011-09-20（万方平台首次上网日期，不代表论文的发表时间）