Synthesis and Characterization of Energetic Ethylene-Bridged Bis(nitroiminotetrazolate) Salts

摘要：

The synthesis of high energy density materials with ethylene bis(nitroiminotetrazolate) as the anions is reported. The energetic salts were readily synthesized by reacting 1,2-bis(5-nitro-iminotetrazol-1-yl)ethane with ammonium hydroxide, hydrazine hydrate, guanidine nitrate, and dihydrazinotetrazine in water. Bis(5-aminotetrazolium) ethylene bis(5-nitroiminotetrazolate) salt was obtained by reacting bis(ammonium) ethylene bis(5-nitroiminotetrazolate) with 5-aminotetrazolium nitrate in water. All salts were fully characterized by IR, and 1H, 13C NMR spectroscopy as well as elemental analyses. In addition, the structural of 1,2-bis(5-nitroimino-1H-tetrazol-1-yl)-ethane is confirmed by single-crystal X-ray diffraction analyses.

作者: YI Wenbin WANG Jieping CAI Chun

作者单位: School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China

会议类型: 国际会议

会议名称: 2011 International Autumn Seminar on Propellants,Explosives and Pyrotechnics(2011国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 南京

会议语种:英文

页码: 133-137

在线出版日期: 2011-09-20（万方平台首次上网日期，不代表论文的发表时间）