Kinetics and Mechanisms of Silver Azide Crystals Explosive Decomposition

摘要：

Nowadays there are two different types of models used for the description of the energetic materials explosive decomposition: chain models and thermal explosion models. Azide heavy metals are the unique energetic materials because of their capability to show one of it in case of different initiating agent 1-4. The main purpose of this article is to analyze the different types of the explosive decomposition models for the azide heavy metals initiated by laser pulses, and compare the results of this analysis with the experimental data. It was shown that the most probable models are the bimolecular and the self-imperfection model. Self-imperfection model is a most probable solid state chain model in case of the stationary action. In case of the impulse action, chain reaction bimolecular model describes in adequate mode a number of experimental data and the process criterions. The effects, prescribing in terms of the model, were found out experimentally.

作者: KRIGER Vadim KALENSKII Alexander ANANEVA Marina GRISHAEVA Elena ZYKOV Igor

作者单位: Department of Solid State Chemistry,Kemerovo State University,Krasnaya 6,650043,Kemerovo,Russia

会议类型: 国际会议

会议名称: 2011 International Autumn Seminar on Propellants,Explosives and Pyrotechnics(2011国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 南京

会议语种:英文

页码: 825-831

在线出版日期: 2011-09-20（万方平台首次上网日期，不代表论文的发表时间）