Synthesis and Characterization of Rosinyl Amine Salt Surfactant
Rosin is reputed as green petroleum because it is renewable,not expensive,and environmental friendly. China is rich in rosin resources. In this report,rosin was used as raw material to prepare rosinyl amine salt (RAS) surfactant. The optimal reaction conditions of RAS was modified rosin and dimethylamine mole ratio of 1:2,reaction temperature of 78 ℃ and reaction time of 2 h. The chemical structure of the product was identified by Fourier transform infrared spectroscopy (FTIR),electrospray ionization-mass spectrometry (ESI-MS) and *H nuclear magnetic resonance (NMR) analysis. As a surfactant,it has a critical micellar concentration (CMC) of 7.07×10-5mol/L,a surface tension of 44.36 mN/m,an emulsification activity of 5min,a height of foam of 165 mm,and a foam stability of 143 mm.
Yan Jin Shuangyue Li Shujun Li Lijun Zhang
Key Laboratory of Bio-based Material Science and Technology of Ministry of Education,Northeast Forestry University,26 Hexing Road,Harbin 150040,P.R.China
国际会议
哈尔滨
英文
1888-1891
2011-03-26（万方平台首次上网日期，不代表论文的发表时间）