Roasting, Phase Transformation and Leaching of Valuable Metals in Spent Lithium-Ion Batteries
Leaching behavior of valuable metal elements in roasted spent Lithium-ion batteries was investigated. The pulp of LiCoO2 or Co3O4 mixed with concentrated sulfuric acid and one of sodium sulfate, potassium sulfate or ammonium sulfate was heated at a temperature range of 150℃ to 300℃. The cobalt-containing transformation products of were then subject to dissolution in hot water. The dissolution rate of the products from LiCoO2 was 56.4~100%, and 97.2~100% for the products form Co3O4. The Na2Co(SO4)2·4H2O phases were detected in the transformation products with sodium sulfate, which were easily dissolved into hot water. Moreover, the mixture of roasted residue of spent lithium-ion batteries with concentrated sulfuric acid and sodium sulfate was heated at 300 ℃. Li and Co in the mixture were leached out in hot water, the leaching rates of Cu and Al reached 84.7% and 93.6%, respectively. When roasting temperature is high than 300℃, all these elements reach a high leaching rates, and Cu and Al can be leached out completely.
Xiao-wu JIE Cheng-yan WANG Dun-fang LI Fei YIN Yong-qiang CHEN Yong-qiang YANG
Beijing General Research Institute of Mining & Metallurgy, Beijing, China, 100044
国际会议
The Fifth International Conference on Waste Management and Technology(第五届固体废物管理与技术国际会议)
北京
英文
304-308
2010-11-01（万方平台首次上网日期，不代表论文的发表时间）