The technology optimum and reaction dynamics of the simulative explosive industrial wastewater degradation in supercritical (sub-critical) water

摘要：

Supercritical(sub-critical) water oxidation technology is applied to degrade the explosive wastewater and low its chemical oxygen demand (COD). The technology optimum and reaction dynamics of TNT, RDX, HMX degradation have been investigated. The experiment results show that the optimum degradation technology is: reaction temperature T=648K, reaction time t=5min, the volume proportion of waste water and oxidant H2O2=10:1. Under this condition, COD is 38mg/L and the degradation ratio of COD for TNT, RDX, HMX is up to 98.7%. The results of reaction dynamics show that the velocity constants are 0.0103, 0.0208, 0.0384, and 0.0466 at 573K, 603K, 623K, and 653K respectively. The active energy, pre-exponential factor and average reaction kinetics order are 60.8kJ/mol, 3.84×103, and 1.56 respectively.

作者: Yanhua Ma Xian Zhu Ling Tian Lei yang Xiaolei Liu Yijing Shen

作者单位: Department of Chemical Engineer,Shanghai university.Shanghai, China

会议类型: 国际会议

会议名称: The 4th International Conference on Bioinformatics and Biomedical Engineering(第四届IEEE生物信息与生物医学工程国际会议 iCBBE 2010)

会议地点: 成都

会议语种:英文

页码: 1-4

在线出版日期: 2010-06-18（万方平台首次上网日期，不代表论文的发表时间）