Photocatalytic ozonation of dimethyl phthalate over TiO2 prepared by a hydrothermal method
TiO2 catalyst was prepared by two kinds of different methods. The photocatalytic activity of TiO2 prepared by the hydrothermal method is 2.5 times higher than that by sol-gel in degradation dimethyl phthalate (DMP). The combined photocatalysis with UV irradiation and ozonation (TiO2/UV/O3) process considerably improved mineralization and degradation of dibutyl phthalate compared to combined photocatalysis with UV irradiation (TiO2/UV) process, combined ozonation with UV irradiation (UV/O3) process and ozonation alone (O3) process. DMP can be quickly mineralized in TiO2/UV/O3, its mineralization process followed Langmuir-Hinshelwood model. Its rate constant k is 0.42 mg/(L·min) and Langmuir adsorption coefficient K is 0.0417 L/mg.
YuanJing Laisheng Li Qiuyun Zhang
School of Chemistry & Environment South China Normal University Guangzhou, China
国际会议
成都
英文
1-4
2010-06-18(万方平台首次上网日期,不代表论文的发表时间)