A New Method of Synthesizing Thiol-functionalized Silica and Its Fixation of Hg(II) in Water
Thiol-functionalized silica was successfully synthesized by cheaper chloropropyl trichlorosilane and NaHS instead of expensive 3-Mercaptopropyltriethoxysilylane agent. The silica-SH and its precursor were characterized by BET, FT-IR, TOC and element analysis. Surface coverage density of silicachloropropyl and silica-SH was 2.5mmol/g and 1.56mmol/g, respectively. The silica-SH was used as sorbent to fix heavy metal ions--Hg(Ⅱ), and showed great potential for fixation of Hg (Ⅱ) from water, the saturation adsorption capacity for Hg(Ⅱ) reached as high as 0.235mmol/g.
Su Jixin Zhang Shenping Zhang Mingbo Dong Feifei Qu Wen
School of Environmental Science and Engineering of Shandong University JiNan, China North Sea Marine Forecast Center of State Oceanic Administration QingDao,ShangDong
国际会议
成都
英文
1-4
2010-06-18(万方平台首次上网日期,不代表论文的发表时间)