SYNTHESIS AND SOLUTION CHARACTERIZATIONS OF POLYPHOSPHAZENES WITH DIFFERENT SIDE GROUPS

摘要：

We have synthesized several kinds of polyphosphazenes through ring-opening polymerization, and later by reacting with sodium alkoxide and sodium phenolate. These polymers have high M_w up to 5×10~6. Then they were studied by gel permeation chromatography (GPC) coupled with multidetectors including a viscometer、 a multiangle laser light scattering (MALLS) andin and a 90° angle dynamic laser light scattering in THF(with 0.1% tetra-nbutylammonium bromide) at 35℃. The results showed that hydrophobic polymers polydiphenoxyphosphazene(PDPP) and polydiethoxyphosphazene(PDEP) had the same Rg/Rh=1.80. The scaling relations of these polymers were

作者: Xuan Chen Xiangling Ji Shuqin Bo

作者单位: State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, P.R.China

会议类型: 国际会议

会议名称: PP’2010，Jinan International Symposium on Polymer Physics(2010济南国际高分子物理学术研讨会)

会议地点: 济南

会议语种:英文

页码: 319-320

在线出版日期: 2010-06-06（万方平台首次上网日期，不代表论文的发表时间）