SYNTHESIS AND CHARACTERIZATION OF A NEW NOVEL HIGHLY THERMOSENSITVE POLYDIMETHYLSILOXANE SUPRAMOLECULAR AGGREGATE
(0) Supramolecular aggregate is a relatively novel and fascinating area in polymer science1. Advanced supramolecular aggregate is expected to be extraordinary superiority over traditional polymers due to their tunable and recyclable characteristics. The dynamic properties in response to the environmental change are outstanding feature of the sophisticated new materials. However, many materials of strongly binding supramolecular motifs have the thermodynamic and kinetic stability, which were the possible drawbacks for the development of thermally responsive polymers in the solid state. Herein, we synthesized a novel thermosensitve material, polydimethylsiloxane supramolecular assembly (PDMSSMA, Figure 1). PDMS-SMA is controlled by weak and labile hydrogen-bonding motifs and π-π stacking, which exhibit highly thermosensitve.
Yang Wang Jie Zhang Shenevu Feng
Key Laboratory of Special Functional Aggregated Materials, Ministry of Education School of Chemistry and Chemical Engineering, Shandong University, Jinan, PR China
国际会议
PP’2010，Jinan International Symposium on Polymer Physics(2010济南国际高分子物理学术研讨会)
济南
英文
334-335
2010-06-06（万方平台首次上网日期，不代表论文的发表时间）