ETHYLENE OLIGOMERIZATION RESEARCH OF Ni(H)/PNP /MAO CATALYST SYSTEM

摘要：

Ni based oligoraerization catalyst has become research focus since SHOP(1) process industrialized. Traditionally, Ni(Ⅱ) cation complexed with N or P type neutral ligand(2) and NO or PO type anion ligand(3-4). PNP type bidentate ligand was a novel compound which has a great application in ethylene oligomerization,especially complex with Cr(Ⅲ)(5-8) but its application related other transition metal has not be mentioned. In this paper,we systhesized 3 PNP ligands L1 ,L2 and L3 , and complexed them with Ni(Ⅱ) to get Cl ,C2 and C3 as ethylene oligomerization catalyst precursor respectively, which use MAO as cocatalyst catalyzed ethylene oligomerization.

作者: Wane Libo Huang Filling Wang Sihan Zhang Baojun

作者单位: Daqing Petrochemical Research Center of PCCL,Daqing 163714,China

会议类型: 国际会议

会议名称: International Symposium on Polymer Chemistry(第四届国际高分子化学学术研讨会 PC 2010)

会议地点: 苏州

会议语种:英文

页码: 243-244

在线出版日期: 2010-06-02（万方平台首次上网日期，不代表论文的发表时间）