Synthesis and characterization of a novel preceramic polymer to Si/B/N/C ceramic fiber

摘要：

A novel preceramic polymer to Si/B/N/C fiber was obtained via co-condensation polymerization between the monomer Si(CH3NH)4 and B(CH3NH)3, which were prepared from NH2CH3 and SiCl4, NH2CH3 and BCl 3 , respectively. The monomers and preceramic polymer were investigated by means of NMR, FTIR and EA. The results showed the monomers were in accordance with the expected structure of Si (CH3NH)4 and B (CH3NH)3. The preceramic polymer exhibits Si-N and B-N bonds while the monomer units were linked through -N(CH3)-.

作者: ZHANG Hui HAN Keqing HAN Keqing YUAN Jia PENG Yuqing YU Muhuo

作者单位: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donhua University,Sh State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donhua University, S

会议类型: 国际会议

会议名称: 2009 International Conference on Advanced Fibers and Polymer Materials(2009年先进纤维与聚合物材料国际学术会议)

会议地点: 上海

会议语种:英文

页码: 455-457

在线出版日期: 2009-10-21（万方平台首次上网日期，不代表论文的发表时间）