Synthesis and characterization of transition metal-containing polyamides
Well-characterized metal-containing polymers have led to a rapidly expanding interest in their properties and potential applications. The incorporation of metal atoms into synthetic polymer chains leads to macromolecular structures in which metals are not only incorporated via the use of traditional covalent bonds but also by potentially reversible coordination interactions. In our work, a transition metal coordination complex monomer was prepared firstly, by the reaction of CuCl2·2H2O and p-aminobenzoic acid at room temperature. This monomer complex has been structurally characterized by elemental analysis, IR and single-crystal X-ray diffraction. Novel metal-containing polyamide was synthesized by the polycondensation of complex monomer containing carboxylic group and p-phenylene diamine. The structure and property of this transition metal-containing polymer were characterized by IR and inherent viscosity.
ZHU Peiju WANG Ying ZHANG Linping XU Hong MAO Zhiping
Key Laboratory of Science & Technology of Eco-Textile (Ministry of Education) Donghua University, Shanghai 201620, P.R.China
国际会议
2009 International Conference on Advanced Fibers and Polymer Materials(2009年先进纤维与聚合物材料国际学术会议)
上海
英文
893-895
2009-10-21（万方平台首次上网日期，不代表论文的发表时间）