Synthesis of Uniform Mesoporous γ-Al2O3 Using Rosin-based Quaternary Ammonium Salt as a Directing Agent
Aluminas with uniform mesoporous structures were synthesized using rosin-based quaternary ammonium salt as a directing agent for the first time, and their structures were characterized with X-ray diffraction and N2 adsorption and desorption. It was indicated from the test results that the surface areas and pore diameters of the mesoporous γ-Al2O3 calcinated at 650 ℃ were in the range of 194 ~213 m2g-1 and 4.18~5.18 nm, respectively, and the content of the rosin-based quaternary amonium salt gave significant influence on the textural properties of the aliminas.The addition of suitable amount of rosin-based quaternary ammonium salt endowed the aluminas with large pore diameter and narrow pore distribution.
mesoporous alumina rosin-based quaternary ammonium salt γ-Al2O3
Peng WANG Zhen-dong ZHAO Liang-wu BI Yu-xiang CHEN
Institute of Chemical Industry of Forest Products, CAF National Engineering Lab for Biomass Chemical Utilization Key and Open Lab on Forest Chemical Engineering, SFA, Nanjing 210042, PR China
国际会议
南京
英文
357-361
2010-10-22(万方平台首次上网日期,不代表论文的发表时间)