Research on Preparation of Flame Retardant Epoxy Containing-Phosphorus by Glycerol

摘要：

This paper reports research on the synthesis and characterization of Triglycidyl phosphate (TGP) taking the glycerol as raw material. 3-chlorine-1, 2-trimethylene glycol (3-MCPD) was firstly prepared through chlorination of the glycerol and hydrochloric acid, and then reacted with solid sodium hydroxide, cyclization forming glycidol. Finally, the trichloro-oxygen phosphorus and the glycidol reacted to produce TGP at low temperature by selecting triethylamine as reagent for neutralizing the acid. The epoxy value of the product is about 0.9 eq/100g. The samples as-synthesized were characterized by IR, GC-MS and H-NMR.

关键词： Epoxy resin containing-phosphorus Glycidol Glycerol GC-MS

作者: Di LI Zhen-shuo CHENG Xin-bao ZHU

作者单位: College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China China Anhui Xinyuan Chemical Co. ltd. Huangshan, 245061, China College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China Anhui Xinyuan C

会议类型: 国际会议

会议名称: International Conference on Chemical and Biological Utilization of Biomass Resources 2010(2010年生物质资源化学利用国际学术研讨会)

会议地点: 南京

会议语种:英文

页码: 536-543

在线出版日期: 2010-10-22（万方平台首次上网日期，不代表论文的发表时间）