TRANSPORT PROPERTIES OF MOLECULAR-CLUSTER MIXTURES OF GASES
In dense gases thermal motions and interactions not only molecules but also of clusters as a dimers, trimers, quadromers created (determine) properties of gases. In cluster model each gas is considered as multicomponent molecular-cluster mixture. The kinetic theory of multicomponent mixtures in which features of molecular-cluster mixtures taken into account to the description of transport properties of such mixtures is applied. Calculations have shown, that in dense gases there is an area of mesoscopical phase transition in which transport coefficients and baroeffects have properties which are inherent for a liquid. The reasons of occurrence of mesoscopical properties that big clusters impose to gas of property of a liquid (Kurlapov, 2005). It is especially shown at collisions of big clusters with molecules and small clusters in molecular-cluster mixtures.
Kurlapov L.I.
Department of General and Theoretical Physics, Satpaev National Technical University of Kazakhstan, 050013 Almaty, Republic of Kazakhstan
国际会议
The Ninth Asian Thermophysical Properties Conference(第九届亚洲热物理性能会议 ATPC 2010)
北京
英文
51-57
2010-10-19(万方平台首次上网日期,不代表论文的发表时间)