HEAT CAPACITIES AND THERMODYNAMIC PROPERTIES OF N-(TERT-BUTOXYCARBONYL)-L-PHENYLALANINE (C14H19NO4)

摘要：

The heat capacities of N-(tert-Butoxycarbonyl)-L-phenylalanine, as an important chemical intermediates used to synthesize proteins and polypeptides, were measured by means of a fully automated adiabatic calorimeter over the temperature range from 80 K to 350 K. The measured experimental heat capacities were fitted to a polynomial equation as a function of temperature. The thermodynamic functions, (HT -H298.15 K) and (STS298.15 K), were calculated based on the heat capacity polynomial equation in the temperature range of (80 to 350) K with an interval of 5 K. The thermal stability of the compound was further studied using TG and DSC analyses; a possible mechanism for thermal decomposition of the compound was suggested.

作者: Jun-Ning Zhao Li-Xian Sun Zhi-Cheng Tan

作者单位: Materials and Thermochemistry Laboratory Dalian Institute of Chemical Physics Chinese Academy of Sci China Ionic Liquid Laboratory and Thermochemistry Laboratory Dalian Institute of Chemical Physics Ch

会议类型: 国际会议

会议名称: The Ninth Asian Thermophysical Properties Conference(第九届亚洲热物理性能会议 ATPC 2010)

会议地点: 北京

会议语种:英文

页码: 904-909

在线出版日期: 2010-10-19（万方平台首次上网日期，不代表论文的发表时间）