Friedel-Crafts acylation of anisole catalyzed by green, reusable hydroxyapatite-zinc bromide catalyst

摘要：

This study was aimed at the development of a green and reusable catalyst for Friedel-Crafts acylation.Firstly,Hydroxyapatite (HAP) and Hydroxyapatite-zinc bromide (HAP-ZnBr2) have been prepared by the co-precipatation method and hydrothermal method respectively.Their structures were characterized by X-ray Diffraction (XRD),Brunauer-Emmett-Teller (BET) and Infrared Spectroscopy (IR).The catalytic efficiency of HAP-ZnBr2 was examined for Friedel-Crafts acylation of anisole.The results showed that the catalyst was green,high activity,high selectivity and it could be reused at least 5 times without obvious activity loss.

关键词： Friedel-Crafts arylation Anisole Hydroxyapatitezinc bromide Catalyzed

作者: Wei Benmei Zhang Zhiyong Dai Zhiqun

作者单位: School of Chemical and Environmental Engineering, Wuhan Polytechnic University,Wuhan,430023, China School of Chemical and Environmental Engineering, Wuhan Polytechnic University,Wuhan, 430023, China

会议类型: 国际会议

会议名称: 2010 International Conference of Environment Materials and Environment Management(2010年环境材料与环境管理国际学术会议 EMEM 2010)

会议地点: 哈尔滨

会议语种:英文

页码: 18-21

在线出版日期: 2010-07-24（万方平台首次上网日期，不代表论文的发表时间）