Synthesis of nanostructural silica using quaternary ammonium salt of lignin as template

摘要：

Cationic surfactant,quaternary ammonium salt of lignin,was synthesis from the lignin and trimethylamine though Mannich Reaction.Then quaternary ammonium salt of lignin was used as a novel template to prepare nanostructural silica from TEOS by sol-gel templating method.After removing the template at 580℃,nanostructural silica were obtained.The results of SEM and TEM show that there were two kinds of the silica after calcined.One is 3-dimetional macroporous silica,with the pore size of 100-200 nm.The other kind of silica is nanoparticle: the particle sizes range from 20 to 200nm and the specific surface area is 387.6 m2·g-1.

关键词： quaternary ammonium salt of lignin silica nanostructure sol-gel

作者: Yu Fangdan Guo Yuanru Fang Guizhen Liu Zhiming

作者单位: College of Material Science and Engineering,Northeast Forestry University,Harbin,Heilongjiang Province,China,150040

会议类型: 国际会议

会议名称: 2010 International Conference of Environment Materials and Environment Management(2010年环境材料与环境管理国际学术会议 EMEM 2010)

会议地点: 哈尔滨

会议语种:英文

页码: 1045-1048

在线出版日期: 2010-07-24（万方平台首次上网日期，不代表论文的发表时间）