Synthesis and characterization of dehydroabietic-based phosphate betaine type amphoteric surfactant
N-(3-dehydroabietyloxy-2-hydroxy) propyl-N,N-dimethyl (2-hydroxy) phosphate betaine was synthesized through the 3-dehydroabietyloxy-2-hydroxypropyl chloride and tertiary amine intermediate by using dehydroabietic acid as raw materials.The structure of the target product was confirmed by FT-IR,1H NMR.The surface-active property was investigated by surface tension experiment.The surface activity of the mixed system of the product and sodium dodecyl sulphate (SDS) was determined.The results showed that critical micelle concentration (CMC) of the product was 1.34 mmol·L-1.Strong synergism in product was observed combining with SDS,and the optimum synergism was obtained at the molar ratio of 1:1.
dehydroabietic acid N-(3-dehydroabietic-2-hydroxy)propyl-N N-dimethyl (2-hydroxy) phosphate betaine amphoteric surfactant
YINFENG ZHAO GUIZHEN FANG
Key laboratory of Bio-based Material Science and Technology,Northeast Forestry University,Heilongjiang,150040,China
国际会议
哈尔滨
英文
1657-1660
2010-07-24(万方平台首次上网日期,不代表论文的发表时间)