A SPIRODIENONE COMPOUND WITH A β-1 LINKAGE FORMED BY OXIDATIVE CROSS COUPLING OF SINAPYL ALCOHOL γ-ACETATE WITH A SYRINGYL LIGNIN MODEL COMPOUND

摘要：

A novel lignin model compound for the syringyl type of spirodienone structures (β-1/α-O-α) was obtained by oxidative coupling of sinapyl alcohol γ-acetate with 1-(4-hydroxy3,5-dimethoxyphenyl)ethanol. The 1H and 13C NMR chemical shifts for the acetate of the model compound were compared with the signals on HSQC NMR spectrum of acetylated avicenia lignin (MWL). The 1H and 13C chemical shifts of signals from α,β, and γpositions in one side chain part of the model were in well agreement with the corresponding correlation signals for spirodienone structures on the HSQC spectrum of the lignin.

关键词： lignin spirodienone β-1 structure syringyl NMR

作者: Takuya Akiyama Jun Kikuchi Tomoya Yokoyama Yuji Matsumotov

作者单位: Wood Chemistry Laboratory, Department of Biomaterial Sciences, Graduate School of Agricultural and L RIKEN Plant Science Center, 1-7-22 Suehiro-cho, Tsurumi-ku, Yokohama-shi 235-0045, Japan

会议类型: 国际会议

会议名称: 16th International Symposium on Wood,Fiber and Pulping Chemistry(第十六届木材、纤维及制浆化学国际会议)

会议地点: 天津

会议语种:英文

页码: 349-352

在线出版日期: 2011-06-08（万方平台首次上网日期，不代表论文的发表时间）