HOMOGENEOUS BUTYRYLATION AND LAUROYLATION OF POPLAR WOOD IN THE IONIC LIQUID 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE

摘要：

Wood meal was dissolved under identical conditions in the ionic liquid l-butyl-3-methylimidazolium chloride (G4mimCl) and homogeneously esterified with butyryl chloride and lauroyl chloride in the presence of triethylamine as a neutralizer. The effect of the molar ratio of reagent to the hydroxyl groups in wood on the properties of the esterified wood and the possible mechanism of the homogeneous esterification of wood in this reaction medium were studied. Furthermore, the physicochemical properties of the esterified wood were characterized by FT-IR, solid-state CP/MAS 13C-NMR, TGA/DTG and SEM. The results confirmed that the homogeneous modifications were successfully processed and highly substituted wood esters could be obtained by reacting the dissolved wood in this homogeneous system.

关键词： esterification ionic liquid butyryl chloride lauroyl chloride poplar wood

作者: Tongqi Yuan Shaoni Sun Feng Xu RuncangSun

作者单位: Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083, China Institute of Biomass Chemistry and Technology, Beijing Forestry University, Beijing 100083, China St

会议类型: 国际会议

会议名称: 16th International Symposium on Wood,Fiber and Pulping Chemistry(第十六届木材、纤维及制浆化学国际会议)

会议地点: 天津

会议语种:英文

页码: 829-834

在线出版日期: 2011-06-08（万方平台首次上网日期，不代表论文的发表时间）