STUDY ON THE KINETICS OF FENTON OXIDATION FOR TREATMENT OF PULPING MIDCOURSE EFFLUENT

摘要：

In this paper,the kinetics of Fenton oxidation for pulping midcourse effluent treatment is studied.An equation for calculating the four unknown parameters involved in the kinetics in the experiment is established.The effects of temperature,concentrations of Fe2+ and hydrogen peroxide on the COD removal efficiency are investigated.The results show that the reaction orders of hydrogen peroxide and ferrous sulfate are 0.2108 and 22.852,respectively,the activation energy is 14616 KJ/mol,and the preexponential factor K is 18.349 under normal treatment temperature.COD removal efficiency and the reaction rate constants are significantly affected by the temperature as well as the concentrations of hydrogen peroxide and ferrous sulfate.Under normal temperature,the dynamic model of pulping midcourse effluent treatment for moderate concentration is asfollows: dCOD/d/=18.349 exp(-14616/RT)H2O20.2108FeSO422.852.

关键词： pulping midcourse effluent fenton oxidation kineticss

作者: Shan H.Lan Xiu W.Wu

作者单位: College of Chemistry and Environmental Engineering,Dongguan University of Technology,Dongguan523808,China.

会议类型: 国际会议

会议名称: 16th International Symposium on Wood,Fiber and Pulping Chemistry(第十六届木材、纤维及制浆化学国际会议)

会议地点: 天津

会议语种:英文

页码: 1420-1423

在线出版日期: 2011-06-08（万方平台首次上网日期，不代表论文的发表时间）