Study on Thermal Hazard of Cyclohexanone Peroxide
The thermal decomposition of pure cyclohexanone peroxide (CYHPO) and its mixture with ethylene glycol, iso-caprylic acid or n-butanol is studied by Accelerating Rate Calorimeter (ARC). The characteristic curves and parameters of adiabatic decomposition are obtained, and the activation energy of the reaction is also calculated. After correction and analysis of the measured data, it can be concluded that the thermal decomposition of pure CYHPO is characterized by low temperature and high decomposition rate, which is very dangerous, but the addition of proper solvent to pure CYHPO can promote evidently the thermal stability of CYHPO and lower dramatically the thermal hazard of CYHPO decomposition.
cyclohexanone peroxide accelerating rate calorimeter thermal hazard
ZHU Peng LIU Huiping ZHOU Bo LIU Zhangrui LIU Yingxue
School of Urban Construction and Safety Engineering, Shanghai Institute of Technology, Shanghai 2002 School of Marine Environment and Safety Engineering, Shanghai Maritime University, Shanghai 201306,
国际会议
The 2010 International Symposium on Safety Science and Technology(2010 安全科学与技术国际会议)
杭州
英文
1064-1070
2010-10-26（万方平台首次上网日期，不代表论文的发表时间）