Study on the Morphology and Damping Properties of the Organic Hybrids of Chlorinated Polyethylene and Hindered Phenol
In this article,the miscibility,intermolecular interaction and damping properties of hybrids consisting of 2-methylene-bis-(4-m-ethyl-6-cyc ohexyl-phenol) (ZKF) and chlorinated polyethylene (CPE) have been investigated by DSC,FTIR and DMA. The results of DSC displayed that the ZKF and CPE were miscible in the amorphous state. The analysis of Kwei equation implied that there was a strong intermolecular interaction between ZKF and CPE. A small molecule ZKF may form two hydrogen bonds with two CPE chains at the same time,and the hydrogen bonding network was existed in the hybrids. The energy dissipation due to dissociation of the intermolecular hydrogen-bond network was larger than that of due to general friction between polymer chains,the loss peak increased dramatically and the position of the loss peak shifted high temperature region.
Hydrogen bonding interactions Damping properties Organic hybrids
Xinbo Ding Tao Liu Jian Han
College of Material & Textile Engin.,Zhejiang Sci-Tech University,Hangzhou 310018,China Key Laboratory of Advanced Textile Materials and Manufacturing Technology,Ministry of Education of C
国际会议
杭州
英文
149-152
2010-10-20（万方平台首次上网日期，不代表论文的发表时间）