Synthesis of Ethilenic Bond Cyclodextrin and Their Application on Silk

摘要：

The cyclodextrin monomer with ethilenic bonds Mono(2-O-tosyl)-6-acryloyl-β-cyclodextrin (β-CD-2-OTs-6-A) and 6-acryloyl-β-cyclodextrin (β-CD-6-A) were respectively synthesized. β-CD-2-OTs-6-A was prepared under the reaction between propylene chloride and β-CD-2-Ots. β-CD-6-A was synthesized by the reaction between propylene chloride and β-CD. The most suitable pH value for β-CD-6-A to be grafted on to silk fabric was proved to be 5. As the single-factor experimental study shows, the optimum process conditions of graftpolymerization about β-CD-2-OTs-6-A are as follows: concentration of monomers, 20％.owf; concentration of potassium persulfate, 1.85％.owf; material to liquor ratio, 1:50; time, 30min; temperature, 80℃; pH, 5. The scanning electron microscope pictures have proven the monomer success stem grafting to the surface of silk.

关键词： propylene chloride cyclodextrin graft silk

作者: FANG Xi HUANG Liangchen ZHAO Shuhui YAN Yinyin

作者单位: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, P.R.China National Engineering Research Center for Dyeing and Finishing of Textiles, Donghua University,Shanghai 201620, P.R.China

会议类型: 国际会议

会议名称: The 12th International Wool Research Conference(第十二届国际羊毛会议12th IWRC)

会议地点: 上海

会议语种:英文

页码: 261-266

在线出版日期: 2010-10-19（万方平台首次上网日期，不代表论文的发表时间）