Catalytic Hydrolysis of NaBH4 with Ni-Co-B Catalysts for In-situ Hydrogen Supply of Proton Exchange Membrane Fuel Cell
Introduction Nowadays, the proton-exchange membrane fuel cell (PEMFC) is attracting widely attention as a zero-emission high efficient energy source. In-situ hydrogen supply technique is one of the key issues for the commercialization of the PEMFC. Recently, hydrogen generation from NaBH4 hydrolysis is proved to be a feasible hydrogen supply method for the PEMFC 1, which can be promoted by using ex-situ 1-3 or in-situ 4 synthesized catalysts during the hydrogen generation reaction. Also, the by-product NaBO2 is environmentally clean and can be recycled for synthesizing NaBH4. In this paper, Ni-Co-B catalysts are introduced and discussed, and proved to be good candidates for catalyzing the hydrolysis of NaBH4 owing to their good catalytic activity and low cost.
Chuan Wu Ying Bai Feng Wu Dan-xian Liu Bao-lian Yi
School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing, 100081 Lab of PEMFC Key Material and Technologies, Dalian Institute of Chemical Physics, Chinese Academy of
国际会议
6th International Conference on Environmental Catalysis(第六届国际环境催化大会 ICEC 2010)
北京
英文
106-106
2010-09-12(万方平台首次上网日期,不代表论文的发表时间)