Catalytic Activity and Recycle Use of Supported Amorphous Co-B Catalysts in Hydroformylation of 1-Octene

摘要：

Introduction The hydroformylation of olefins with syngas to aldehydes has been an important industrial chemical process, which annually produces 7 million tons of aldehydes. Applying immobilized catalysts or solid catalysts to the hydroformylation of olefins is a very meaningful work for the heterogenization of homogeneous catalytic processes. Metal-metalloid amorphous alloy catalysts have shown high activity and selectivity in some hydrogenation processes. In our early research, we found that the pure amorphous Co-B catalyst exhibited relatively high activity in the hydroformylation of 1-octene. In this work, we employed several supported amorphous Co-B catalysts in octene hydroformylation, and studied their catalytic performance and recycle use.

作者: Junying Long Dehua He

作者单位: Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China

会议类型: 国际会议

会议名称: 6th International Conference on Environmental Catalysis(第六届国际环境催化大会 ICEC 2010)

会议地点: 北京

会议语种:英文

页码: 271-271

在线出版日期: 2010-09-12（万方平台首次上网日期，不代表论文的发表时间）