Effect of samarium on the photocatalytic property of Sm-TiO2/CNFs composites
Composites of Sm doped TiO2 nanoparticles dispersed on carbon nanofibers (Sm-TiO2/CNFs) with different Sm contents were prepared by preoxidation, hydrolyzation and calcination of Sm-TiO2 precursor/PAN nanofibers. The characterizations of SEM, EDX, XPS and XRD showed that the CNFs surface was loaded by Sm-TiO2 nanoparticles with a uniform size of about 10nm, existing as anatase. It was concluded from XPS results that Ti element exist as Ti4+ and Sm doping increased the content of absorbed oxygen in composites. The effect of Sm doping on the photocatalytic activity of the Sm-TiO2/CNFs composite was investigated by the photocatalytic degradation of methyl orange aqueous solution under UV irradiation. It was found that Sm doping could improve the photocatalytic property of Sm-TiO2/CNFs effectively compared with the undoped specimen, and the photocatalytic activity of the Sm-TiO2/CNFs samples enhanced firstly and then reduced with Sm content increasing.
TiO2 Sm-doping carbon nanofibers photocatalyst electrospinning
Liying Zhu Xiaoping Yang Donghua Teng Yunhua Yu
The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, PR China
国际会议
青岛
英文
541-544
2009-10-09(万方平台首次上网日期,不代表论文的发表时间)