LEVELS OF PCDDS, PCDFS, DIOXIN-LIKE PCBS, AND PBDES IN FISH SAMPLES FROM RIVERS AND ESTUARIES IN TAIWAN
The concentrations of polychlorinated dibenzo-p-dioxin (PCDDs), polychlorinated dibenzo- p-furan (PCDFs), dioxin-like polychlorinated biphenyls (DLPCBs), and polybrominated diphenyl ethers (PBDEs) were measured in fifty-nine fish samples collected from rivers and estuaries in Taiwan. Determination of PCDDs/PCDFs/ DLPCBs and PBDEs was carried out using HRGC/HRMS. For all fish of all species from all sampling areas, the concentration range for PCDDs/PCDFs and DLPCBs World Health Organization Toxic Equivalent (WHO-TEF) were 0.024 ～ 1.02 pg WHO-TEQ/g wet weight and 0.023 ～ 14.1 pg WHO-TEQ/g wet weight respectively. The concentration range for PBDEs were 12.1 ～ 380 ng/g lipid weight, with BDE-47>BDE-154>BDE-100 ～ BDE-99>BDE-153>BDE-183. The highest concentrations of both PCDDs/PCDFs and PBDEs were found in the area of Erren river and the highest concentrations of DLPCBs was found in Dahan river. The average recoveries of the 13C-labelled internal standards for PCDDs/PCDFs, Dioxin-like PCBs and PBDEs were in the range of 63 ～ 95 ％, 54 ～ 78 ％ and 37 ～ 126 ％ respectively. The average recoveries of the method blank spike samples for PCDDs/PCDFs, Dioxin-like PCBs and PBDEs were in the range of 86 ～ 99 ％, 105 ～ 112 ％ and 86 ～ 119 ％ (133％ for BDE-209) respectively.
Peng J H Wu C P Lee T Y Chen Y W Lin Y Y Hsu Y C Tsai C L Weng Y M
Environmental Analysis Laboratory,Environmental Protection Administration,Executive Yuan,No. 260,Sec. 3,Ming Tsu Rd,Chung-Li City,Taoyuan County,32024
国际会议
北京
英文
1-4
2009-08-24（万方平台首次上网日期，不代表论文的发表时间）