Suppression of PCDD/Fs formations by addition of hydrocarbons during combustion of chlorinated phenols

摘要：

The thermal reactions of 2,4,6-T3CP with hydrocarbons in a dry air stream was investigated using a silica flow reactor at residence time of 10 s and temperature range from 450 to 850 ℃. The maximum molar yields of PCDD/Fs were observed at 650 ℃ on the combustion of each chlorinated phenol. Addition of hydrocarbons to chlorinated phenols showed remarkable decreasing in the yields of PCDD/Fs. The suppression effect on the formations of PCDD/Fs was dependent on the mixing ratio of hydrocarbons. Short-chain hydrocarbon showed relatively high suppression ratio. The pyloritic products of hydrocarbons, such as alkyl radical and hydrogen radical would directly affect on the suppressing of PCDD/Fs formations during combustion of chlorinated phenols.

作者: T.Kishi S.Suzuki T.Kawakami K.Takeda S.Onodera

作者单位: Faculty of Pharmaceutical Sciences,Tokyo University of Science,2641 Yamazaki,Noda,Chiba 278-8510,Jap Division of Medical Devices,National Institute of Health Sciences,1-18-1 Kamiyoga,Setagaya-ku,Tokyo

会议类型: 国际会议

会议名称: 29th International Symposium on Halogenated Persistent Organic Pollutants(第29届国际持久性有机污染物研讨会)(2009国际二噁英大会)

会议地点: 北京

会议语种:英文

页码: 1-6

在线出版日期: 2009-08-24（万方平台首次上网日期，不代表论文的发表时间）