Influences of metal oxides on the formation／destruction of PCDD／Fs during combustion of 2，4，6-trichlorophenol in a model incinerator
The influences of metal oxides on the formation/destruction of PCDD/DFs during combustion of 2,4,6-trichlorophenol(2,4,6-T3CP)gases were investigated by passing through over a metal oxide bed(5％ by mass metal oxide/silica powder)over a temperature ranging of 300-800℃ using a quartz tube reactor The evolved gaseous analyses showed that 1,3,6,8-and 1,3,7,9-tetrachlorodibenzo-p-dioxins(T4CDDs)were the predominant products,with the maximum yield at 650℃. In the TCDD formation-temperature curve, during combustion of 2,4,6-T3CP gases by passing through the silica gel bed alone.The maximum peaks in the TCDD formation curves were shifted to lower temperature ranges than 650℃ after passing through 2,4,6-T3CP gases over CuO/SiQ and Fe2O3/SiO2 beds In contrast to the 2,4,6-TCP gases-CuO/SiO2 and Fe2O3/SiO2 reactions,the presence of CaO and ZnO in the bed decrease the yields of TCDD formation over a temperature ranging of 300-800℃ Similar TCDD formation curves that obtained for 2,4,6-T3CP gases alone were observed for the reactions In simultaneous induction of CuO or Fe2O3 and 2,4,6-T3CP into the quarts tube reactor.
Shota Suzuki Tomohiro Kishi Tsuyoshi Kawakami Sukeo Onodera
Graduate School of Pharmaceutical Sciences,Tokyo University of Science,2641 Yamazaki,Noda,Chiba,278- Graduate School of Pharmaceutical Sciences,Tokyo University of Science,2641 Yamazaki,Noda,Chiba,278-
国际会议
北京
英文
1-6
2009-08-24（万方平台首次上网日期，不代表论文的发表时间）