SIMULTANEOUS DETERMINATION OF BISPHENOL A、ALKYLPHENOLS AND THEIR ETHOXYLATES IN WATER AND SEDIMENT OF SONGHUA RIVER, NORTHEASTERN CHINA
A method has been developed and validated, that in order to assess the occurrence of alkylphenols and alkylphenol ethoxylates: 4-tert-octyphenol (OP), 4-n-nonylphenol (NP), nonylphenol mono- to di-ethoxylates (NP1EO, NP2EO), bisphenol A (BPA) in water and sediment samples. The survey was preceded by liquid-liquid extraction for water samples and soxhlet extraction for sediment samples, clean-up and derivatization procedures for the simultaneous GC-MS determination of all examined EDCs. The limits of detection (LOD) of all the target compounds were 0.052～1.2ng/ml. Mean recoveries were higher than 76％ and 72％ for all the target compounds in water and sediment samples, respectively. Relative standard deviations (RSD) were 6-13％ for water and 8-15％ for sediment. The concentration of OP, 4-n-NP, NP1EO, BPA and NP2EO, in water samples of Songhua River were 1.84～15.28 ng/L, 0.18～6.82 ng/L, 6.06～126.09 ng/L, 8.84～329.47 ng/L and 4.68～123.30 ng/L, respectively, and the concentration in sediment samples were 0.69～7.92 ng/g, 0.27～59.54 ng/g, 4.11～696.61 ng/g, 5.12～27.75 ng/g and 9.32～269.76 ng/g dry weight, respectively.
Zhang Z.F. Ren N.Q. Qi.H. Gao.D.W. Li Y.F.
International Joint Research Center for Persistent Toxic Substances (IJRC-PTS),State Key Laboratory International Joint Research Center for Persistent Toxic Substances (IJRC-PTS),State Key Laboratory
国际会议
北京
英文
1-5
2009-08-24（万方平台首次上网日期，不代表论文的发表时间）