GAS CHROMATOGRAPHIC RETENTIONS OF 180 POLYBROMINATED DIPHENYL ETHERS

摘要：

The gas chromatographic (GC) retention times of 180 polybrominated diphenyl ethers (PBDEs) on two commonly used capillary columns, Restek Rtx-1614 and J&W DB-5MS, were obtained under three oven temperature programs. The relative retention times (RRTs) for PBDEs were calculated by normalizing the retention times of individual congeners to the sum of those of BDEs 47 and 183. There are few cross-homolog retention time overlaps for PBDEs. Within the same homolog, ortho-substituted PBDE congeners tend to elute earlier than those with bromines at para and meta positions. Correlation regression equations were established for the relative retention times from the three programs to indicate the feasibility of retention time prediction for other GC conditions.

作者: Wei H Yang R Q Li A

作者单位: School of Public Health,University of Illinois at Chicago,Chicago,Illinois 60612,USA

会议类型: 国际会议

会议名称: 29th International Symposium on Halogenated Persistent Organic Pollutants(第29届国际持久性有机污染物研讨会)(2009国际二噁英大会)

会议地点: 北京

会议语种:英文

页码: 1-6

在线出版日期: 2009-08-24（万方平台首次上网日期，不代表论文的发表时间）