Synthesis and mesomorphism of semi-fluorinated chain liquid crystals with 1,2,3-triazole rings

摘要：

Series of semi-fluorinated chain liquid crystals with 1,2,3-triazole rings have been synthesized with CuI-Et3N catalyzed aikyne-azide cycloaddition reaction. The selectively produced 1,4-disubstituted regioisomers were characterized by using IR, NMR, and Mass. The mesomorphic behaviors were characterized with polarizing optical microscopy and differential scanning calorimetry. Compounds with perfluorinated chains have showed smectic A phase.

关键词： Click chemistry Copper catalyzed Alkyne-azide ycloaddition Semi-fluorinated chain Smectic A phase

作者: Yang Yang Ke-Qing Zhao Wen-Hao Yu Bi-Qin Wang Ping Hu

作者单位: College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, China

会议类型: 国际会议

会议名称: 2009 International Symposium on Liquid Crystal Science and Technology(2009国际液晶科技研讨会)

会议地点: 昆明

会议语种:英文

页码: 135-139

在线出版日期: 2009-08-02（万方平台首次上网日期，不代表论文的发表时间）