Preparation for the Hollow Nickel Fibres of the Positive Current Collector by Electroless Plating Technique
In this experiment, electroless plating method was used to obtain the hollow nickel fibres. Polyacrylonitrile fibres with the diameter about 10μm and 3mm length were chosen as the templates of electroless-plating through screening and optimizing various fibres. Low temperature alkaline solution with the sodium hypophosphite as the reducer was adopted and the optimal parameters were determined. Polyacrylonitrile composite fibres with a dense nickel coating about 5～7 μm thickness were obtained. The plated fibres were then sintered in the air to remove the organic templates. It had been found that the sintering temperature had great influences on the formation of the hollow fibres. The Polyacrylonitrile fibres could not be removed completely at low temperature (300℃), and when the temperature increased to 400℃, no organic fibres could be observed from SEM and the hollow nickel oxide fibres with dense wall were obtained. However, when the sintering temperature further increased to 500℃, great changes had been found, the hollow fibres with brittle porous wall were obtained. A dense and uniform hollow nickel fibres with nickel content higher than 90％ were finally obtained after the hydrogen reduction treatment at the temperature of 750℃ for 2 hours.
Nickel Hydrogen Battery Current Collector Hollow Nickel Fibres Electroless Plating
Juan LIU Yan CHENG Lei ZHU Xuyu JIAN Zhong WANG Haijun YU
General Research Institute for Nonferrous Metals, Beijing 100088, China Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871,China
国际会议
重庆
英文
492-497
2008-06-09（万方平台首次上网日期，不代表论文的发表时间）