Ring Opening Polymerization of ε-caprolactone Catalyzed with Magnesium Lactate

摘要：

The aim of this paper is to present a synthesis method of poly(ε-caprolactone) by the ring opening polymerization of ε-caprolactone catalyzed with nontoxic magnesium lactate. The results indicated that Mg(Lac)2 is a catalyst with moderate activity for the polymerization of ε-caprolactone. Effects of the catalyst and reaction temperatures on the microstructure of the ε-caprolactone and L-lactide copolymers were investigated by means of 13C-NMR spectroscopy. An increase in the reaction temperature enhances the role of transesterification and the extent of randomness.

关键词： Poly(ε-caprolactone) Copolymer Magnesium Lactate

作者: Lian LIU Zhiyong WEI Pei WANG Min QI

作者单位: Department of Materials Science and Engineering, Dalian Maritime University,Dalian 116026, China School of Automotive Engineering, Dalian University of Technology, Dalian 116024, China School of Materials Science and Engineering, Dalian University of Technology,Dalian 116024, China

会议类型: 国际会议

会议名称: 2008年中美材料国际研讨会

会议地点: 重庆

会议语种:英文

页码: 1208-1210

在线出版日期: 2008-06-09（万方平台首次上网日期，不代表论文的发表时间）