Synthesis of New Hybrid Monomers Containing Vinyl Ether and (Methyl) Acryloyl Groups

摘要：

Titanium (Ⅳ) isopropoxide (TIPO) is used as transesterification catalyst, TIPO can be used for a variety of alcohols and esters catalyzed reaction, the use of the catalyst result in short reaction times and good quality products of excellent yield, without the formation of byproducts.in the present of catalyst, with methyl methacrylate and 4-hydroxylbutyl vinyl ether as reactant, 4-(vinyloxy)butyl methacrylate containing cationic and radical polymerizable vinyl groups was synthesized. The influence of reaction factors, such as ratio of ester to alcohol, amount of catalyst, time and temperature of reaction on the ester transesterification was investigated. On the basis of the experiments, the optimum conditions were given.

关键词： Transesterification Hybrid Monomers methyl methacrylate Titanium (Ⅳ) isopropozide

作者: Diao Cuimei Zou Yingquan

作者单位: College of Chemistry, Beijing Normal University, Beijing, P.R.China

会议类型: 国际会议

会议名称: The 31st International Congress on Imaging Science(第31届国际影像科学大会 ICIS2010)

会议地点: 北京

会议语种:英文

页码: 451-453

在线出版日期: 2010-05-12（万方平台首次上网日期，不代表论文的发表时间）