Electrosyntheses of Polyacrylate Functionalized Polyfluorene Network Films with Good Fluorescence Properties
Two novel acrylate-functionalized molecules 9H-fluoren-9-acrylate (FA) and N-9H-fluoren-9-acrylamide (FAM) were designed and successfully synthesized in this paper. As expected, two precursor polymers were prepared by the radical polymerization of the two monomers. Free-standing, conducting conjugated, and polyacrylate functionalized polyfluorene network films were synthesized by the direct anodic oxidation of poly(9H-fluoren-9-acrylate) (PFA) and poly(N-9H-fluoren-9-acrylamide) (PFAM) in CH2Cl2 containing additional 40% (by volume) boron trifluoride diethyl etherate (BFEE) and pure BFEE, respectively. The structures and morphologies of both the monomers and the as-formed polymers were characterized and investigated by 1H NMR, FT-IR, UV-vis, and SEM spectral analyses and measurements, which will be seen in other reports recorded by us. The obtained polyacrylate functionalized polyfluorene network films showed good electrochemical behavior and high thermal stability. Fluorescence spectral studies revealed that the maximum emission peaks of both PFM and PFAM appeared at about 346 nm, while those of polypoly(9H-fluoren-9-acrylate) (PPFA) and polypoly(N-9H-fluoren-9-acrylamide) (PPFAM) in solid state both appeared at about 415 nm, implying the blue-light emitting properties of PPFM and PPFAM, which may find potential applications in organic light-emitting-dioxides (LEDs).
Zhaojin Zhu Jiong Wang Jingkun Xu Meishan Pei
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and TechnologyNormal University, Nancha Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanch School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P.R.China
国际会议
The 31st International Congress on Imaging Science(第31届国际影像科学大会 ICIS2010)
北京
英文
520-522
2010-05-12（万方平台首次上网日期，不代表论文的发表时间）