Study of a Novel Photochromic Diarylethene Dimer with Stable Colored State Only

摘要：

The synthesis and spectral properties of a novel photochromic diarylethene dimer have been studied in this paper. Selective modulation of UV-Vis absorption spectra between the two isomers of the dimer has been carried out by the introduction of a spacer which made a red-shift of the maximum absorption wavelength of ring-open isomer from ultra-violet to visible range and no change of the corresponding ring-closed isomer. Only the colored state of the dimer was stable under the irradiation of sunshine because of much higher ring-closed quantum yield and much lower ring-open one than the diarylethene monomer. The fatigue resistance and thermal stability were also excellent. All these properties have implied it could be a kind of good organic super-RENS mask material.

关键词： photochromic diarylethene dimer synthesis UV-Vis absorption spectra stable colored state only selective modulation

作者: Jiaxiang Yi Guangfei Tan Zihui Chen Fushi Zhang

作者单位: The key Lab of Organic Photoelectrons & Molecular Engineering of Ministry of Education, Department o The key Lab of Organic Photoelectrons & Molecular Engineering of Ministry of Education, Department

会议类型: 国际会议

会议名称: The 31st International Congress on Imaging Science(第31届国际影像科学大会 ICIS2010)

会议地点: 北京

会议语种:英文

页码: 763-766

在线出版日期: 2010-05-12（万方平台首次上网日期，不代表论文的发表时间）